- icamr@sciei.org
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- Mon - Fri 9:30am-18:00pm
Prof. Young Gun Ko
Yeungnam University, Republic of Korea
Speech Title: Toward Materials Architecture on Surface via Plasma Electrolytic Oxidation
Abstract: In recent years, considerable research has long been devoted to the development of metallic materials with excellent surface properties through various surface modification techniques. A plasma electrolytic oxidation (PEO), one of the electrochemical coatings, has considered the eco-friendly wet coating in alkaline-based electrolytes where the surface characteristics of metal would be altered significantly by electrochemical reactions assisted by plasma discharges, resulting in the formation of hard, conformal, adhesive inorganic layer on the metal substrate. This talk will describe a couple of the scientific principles including transient discharge behavior at breakdown, nucleation and growth of inorganic layer, and electrophoresis for incorporating inorganic particle. It will outline the essential microstructural features related to defect structure, plasma-induced structural transformation, phase transition, and roles of inorganic agents. The protective nature of the present coating will be highlighted by considering structural reliabilities, such as tribological and corrosion performances. In addition, the emerging applications arising from functional properties of the present coating, such as biomedical, catalysis, light, and energy performances, will be delivered. The benign approaches used to improve the structural and functional properties of coating layers will be described utilizing pre- and post-treatments of PEO if time will be allowed.
Bio:
Prof. Young Gun Ko has
been working for School of Materials Science
and Engineering, Yeungnam University, Republic of Korea
as a full professor since 2009. Prior to the current
affiliation, he worked for Prof. Suresh group at
Massachusetts Institute of Technology (MIT) where he
investigated nanoscale mechanics of light materials as a
postdoctoral researcher. He had been granted Bachelor,
Master, and Ph.D. diploma from Department of Materials
Science and Engineering, Pohang University of Science
and Technology (POSTECH). Recently, he was responsible
as a Head of Integrated Materials Chemistry Laboratory
for how to improve the electrochemical response of valve
metals via surface reforming based on plasma
electrolysis.
He has worked as Editorial Board for Journal of
Magnesium and Alloys whose impact factor is 15.8. He has
been the Top 2% Scientist by Stanford University since
2020. At present, the SCI paper number and citation
number, and h-index are 283, 10,039, and 52.
Prof. Jian-Gong Ma
Nankai University, China
Speech Title: Composite Catalysts based on Metal-Organic Frameworks
Abstract: Metal-organic frameworks (MOFs) are crystalline porous materials constructed by metal ions and organic ligands, which emerge as one of the most attractive materials in a variety of fields including gas storage/separation, sensing and pollution management. Recently, MOFs have been used in catalysis due to their unique structures and abundant metal active centers. However, it is still a great challenge to improve MOF catalysts with both high activity and high stability. To modify the catalytic activity of selected stable MOFs, we introduced highly active units including nanoparticles, nanowires, clusters and organometallic molecules inside MOF pores to obtain series composite catalysts such as Ag@MIL-101, Ru@ZIF-67, Cu2O@ZIF-8, Fe3O4@ MIL-101(Fe), and NHC-Co@MIL-100, which were used in CO2 conversion, hydrogenation of xylose and reduction of 4-nitrophenol, and synthesis of NH3 with excellent yields, selectivity, high stability and recyclability under extremely mild conditions. Besides, MOFs were also applied as “sustained-release capsules”, which could keep long pot-life during transport at ambient temperature while release active catalytic centers such as Pt for in-situ polymer formation at selected temperature. The composite catalysts exhibit combined superiority of nano-materials, single-molecules and MOFs.
Bio: Prof. Dr. Jian-Gong Ma received both Bachelor and Master degree in chemistry at Nankai University in 2003 and 2006, respectively. After recieving PhD degree in 2011 in Technische Universität Berlin, he went back to China, and joined Nankai university. Currently Jian-Gong Ma is the associate professor and Young academic leader at the department of chemistry, Nankai University. His scientific focus is the synthesis and application of metal-organic frameworks (MOFs) composites, especially in the catalytic conversion of CO2 and green synthesis of industrial and pharmacal productions.
Prof. Emre Erdem
Sabanci University, Turkey
Speech Title: Probing Defect Structures in Materials: Insights through EPR Spectroscopy for Supercapacitor Applications
Abstract:
Electron paramagnetic
resonance (EPR) spectroscopy is a versatile and powerful
technique for investigating defect structures in a wide
variety of materials, particularly oxides, where defects
play a key role in defining their electronic, magnetic,
and optical properties. In this seminar, I will provide
a brief introduction to EPR spectroscopy within the
context of solid-state materials science, focusing on
its ability to study defects in semiconductor
nanomaterials, perovskites, and 2D materials. EPR is not
only effective in characterizing intrinsic and extrinsic
defect states but is also highly sensitive to variations
in crystal field parameters, which differ across
material types—from perovskites like PbTiO3 and
lead-free alternatives to semiconductor systems such as
ZnO nanomaterials. Additionally, EPR offers detailed
insights into the electronic states of metal ions,
making it an extensive technique for determining the
concentration and nature of defect ions, whether they
are extrinsically doped into solids or intrinsically
present. It is also capable of distinguishing between
surface and volume defects, which is crucial for
understanding material behavior in various applications.
We will explore how EPR spectroscopy can uncover
critical details such as ion substitution, charge
compensation, and oxygen vacancies, and discuss how
these insights contribute to the broader understanding
of material properties.
Finally, I will introduce ongoing research where ZnO and
lead-free perovskites are being applied as electrode
materials in all-in-one supercapacitor devices for
energy storage systems. We will examine the relationship
between material properties and device performance,
highlighting how EPR and complementary techniques such
as photoluminescence provide extensive control over
defect states, enabling a deeper understanding of the
functional properties of electrode materials for
sustainable energy technologies.
Figure 1: (left) Defect evolution of non-stoichiometric ZnO. (right) The supercapacitor device based on ZnO and 3D graphene foam electrodes.
Bio: Emre Erdem is now full professor at Sabanci University, Materials Science and Nano Engineering program (Istanbul / Turkey). He obtained his BSc degree from Ankara University Physics Department in 1998. In 2001 and 2006, he received his MSc and Ph.D. Degrees from the University of Leipzig Physics Department, respectively. He did postdoctoral research at the Technical University of Darmstadt between the years 2006-2009. In 2010, he became a research group leader in University of Freiburg on the spectroscopic studies of functional nanomaterials and in 2017 he received his habilitation degree in Physical Chemistry. He was awarded LE STUDIUM / Marie Skłodowska-CurieResearch Fellowship (2017), Eugen Grätz Prize (2011) and DAAD scholarship (1999). He (co-)authored more than 140 publications in international journals and more than 70 invited, plenary or keynote talks in conferences. Research areas: Energy storage, nanomaterials, spectroscopy, defect structures, carbon from wastes, power-to-X.
Prof. Bo Yang
Northeastern University, China
Speech Title: Flat-band Photothermal Conversion Materials for Extraordinary Solar Interfacial Generation
Abstract: The shortage of
freshwater resources is becoming increasingly severe due
to factors such as population growth, environmental
pollution, and climate change [1]. Given that over 70%
of the Earth's surface is covered by oceans, seawater
desalination is undoubtedly the most effective strategy
to address this urgent issue. In recent years,
researchers have been dedicated to exploring
solar-driven interfacial water evaporation technologies
based on the photothermal conversion effect [2-3], which
hold broad application prospects in reducing the
pressure of fossil energy consumption and environmental
pollution, as well as ensuring the safe supply of clean
water resources.
Obtaining photothermal conversion materials with broad
absorption spectra and high absorption rates is the
primary challenge in efficiently converting solar energy
into thermal energy [4-6]. Based on the essence of the
interaction between light and matter, this work employs
first-principles calculations and experimental research
to discover that the Ti-Ti dimer structure present in
titanium suboxides (TinO2n-1) leads to the localization
of Ti-3d electrons in real space and introduces
flat-band electronic states near the Fermi level,
thereby enhancing the joint density of states for
electron transitions [7]. λ-Ti3O5, a metallic material,
exhibits multiple flat-band electronic states
originating from Ti-3d orbitals over a wide energy range
near the Fermi level, resulting in a light absorption
rate of 96.4% across the full solar spectrum.
Using first-principles molecular dynamics simulations,
it is found that the Ti-Ti dimers on the most stable
surface of λ-Ti3O5 can decompose some initially
chemisorbed water molecules into hydroxyl groups (-OH)
and hydrogen (H), which bind to the Ti and O atoms on
the λ-Ti3O5 surface, respectively, leading to the
hydroxylation of the λ-Ti3O5 surface. Moreover, the
unique U-shaped groove structure of this surface
facilitates rapid proton exchange, enabling the
formation of metastable H3O* units within the physically
adsorbed water molecule layer on the hydroxylated
surface. This weakens the hydrogen bonding between water
clusters containing H3O* and their surrounding water
molecules. Combined with experimental validation, this
fundamentally reveals the mechanism of water molecule
evaporation from the λ-Ti3O5 surface in the form of
clusters under light irradiation.
An evaporator with a three-dimensional porous
interconnected structure was fabricated by mixing the
photothermal conversion material λ-Ti3O5 with polyvinyl
alcohol (PVA). Under 1 sun illumination (1 kW/m2), a
water evaporation rate as high as 6.09 kg/m2/h was
achieved. Furthermore, an outdoor seawater desalination
and freshwater collection device was designed, which,
when placed under natural sunlight at the campus of
Northeastern University, achieved an average daily
freshwater collection rate of 23 L/m2, demonstrating
promising application prospects.
Bio:
Prof. Dr. Bo Yang is a full
professor in the School of Materials Science and
Engineering at Northeastern University. He has long been
committed to the basic research on alloy design,
microstructure and property control of phase change
functional materials and photothermal conversion
materials. His research achievements have been published
in more than 60 academic papers in internationally and
domestically renowned academic journals such as Nature,
Acta Materialia, and Scripta Materialia. He has given
two oral reports at international academic conferences.
He has undertaken 2 general projects of the National
Natural Science Foundation of China and 1 sub-project of
the National Key Research and Development Program. He
has applied for and been granted 4 national invention
patents.